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10-10 2022
Nickel-Catalyzed Cross-Redistribution between Hydrosilanes an...         Shaowei Chen,Xiaoqian He,Chenyu Jin,Weilu Zhang,Yuxi Yang,Shanshan Liu,Yu Lan,K. N. Houk,Xiao Shen.Angew.Chem.Int.Ed.(沈晓)Abstract        Silanes are important in chemistry and material science. The self-redistribution of HSiCl3 is an industrial process to prepare SiH4, which is widely used in electronics and automobile industries. However, selective silane cross-redistribution to pr...
09-22 2022
Nickel-Catalyzed Defluorinative Asymmetric Cyclization of Flu... Kuai Wang,Jiachang Chen,Wenfeng Liu, Wangqing Kong.Angew.Chem.Int.Ed.(孔望清)Abstract        The introduction of fluorine-containing groups into organic molecules can significantly affect their physical and chemical properties and has long been used as an effective strategy for drug discovery and development. Consequently, the development of catalytic asymmetric methods for the synthesis of f...
09-16 2022
Photocatalyzed Cascade Reactions of Cyclopropanols andα-Trif...         ​ Yunxiao Zhang,Yunhong Niu,Youyuan Guo,Jiaxin Wang,Yizhi Zhang,Shanshan Liu,Xiao Shen.Angew. Chem. Int. Ed(沈晓)Abstract:        A combination of photoredox catalysis and energy transfer catalysis/direct photo-excitation enables cascade reactions of cyclopropanols andα-CF3-olefins, in which two rings and three bonds are constructed in one reaction, affording fusedgem-difluorooxetan...
08-31 2022
From N-H nitration to controllable aromatic mononitration and...         Tao Yang,Xiaoqian Li,Shuang Deng,Xiaotian Qi,Hengjiang Cong,Hong-Gang Cheng,Liangwei Shi,Qianghui Zhou, and Lin Zhuang.JACS Au(庄林、周强辉、史良伟)Abstract:        Nitroaromatics are tremendously valuable organic compounds with a long history of being used as pharmaceuticals, agrochemicals, and explosives as well as vital intermediates to a wide variety of chemicals. Consequently, t...
08-31 2022
High-Performance Organic Photovoltaic Modules Using Eco-Frien...         Qiang Wu,Yue Yu,Xinxin Xia,Yuhan Gao,Tao Wang,Rui Sun,Jing Guo,Shanshan Wang,Guohua Xie,Xinhui Lu,Erjun Zhou,Jie Min.Joule(闵杰)        Abstract:        The development of the internet-of-thing (IoT) ecosystem has an urgent demand for convenient energy sources, such as indoororganic photovoltaics(IOPVs), to power IoT devices. However, the limited medium band-gap acceptors ...
08-31 2022
Synthesis of Cyclopentene Derivatives via Electrochemically I... ​        Zhipeng Guan,Shuxiang Zhu,Yayu Ye,Xiangwei Li,Yanlong Liu,Pengjie Wang,Prof. Heng Zhang,Dr. Zhiliang Huang,Prof. Aiwen Lei.Angew. Chem. Int. Ed.(雷爱文,张恒,黄志良)        Abstract:        Cyclopentenes are common cores in many natural products, and in bioactive and functional molecules. However, their synthesis remains challenging in terms of harsh conditions, poor selectivity, ...
08-31 2022
Electrophotochemical Ce-Catalyzed Ring-Opening Functionalizat...         Zhaoliang Yang,Dali Yang,Jianye Zhang,Chenyu Tan,Jiajun Li,Shengchun Wang,Heng Zhang,Zhiliang Huang*, and Aiwen Lei*. J. Am. Chem. Soc.(雷爱文,黄志良)        Abstract:        Selective cleavage and functionalization of C–C bonds in alcohols is gaining increasing interest in organic synthesis and biomass conversion. In particular, the development of redox-neutral catalytic methods w...
08-31 2022
Site-selective amination towards tertiary aliphatic allylamin...         Shengchun Wang,Yiming Gao,Zhao Liu,Demin Ren,He Sun,Linbin Niu,Dali Yang,Dongchao Zhang,Xing’an Liang,Renyi Shi,Xiaotian Qi&Aiwen Lei.Nature Catalysis(雷爱文,戚孝天)        Abstract:        Aliphatic allylamines are widely used for the synthesis of diverse building blocks for agrochemicals and pharmaceuticals; there is therefore considerable interest in developing versatile and dir...
07-08 2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ... ​       Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.(沈晓、蓝宇)       Abstract:       Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...
05-17 2022
Dual-Resolving of Lipid Positional and Geometric Isomers of C...        Guifang Feng, Ming Gao, Liwei Wang, Jiayi Chen, Menglu Hou, Qiongqiong Wan, Yun Lin, Guoyong Xu, Xiaotian Qi & Suming Chen.Dual-resolving of positional and geometric isomers of C=C bonds via bifunctional photocycloaddition-photoisomerization reaction system.Nat. Commun.(陈素明)       Abstract:       The biological functions of lipids largely depend on their chemical structures. The po...
05-04 2022
Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Der... ​        Yizhi Zhang,Gang Zhou,Xingxing Gong,Zhuanzhuan Guo, Xiaotian Qi, Xiao Shen.Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Derived Carbenes to Alkenes.Angew. Chem. Int. Ed.(沈晓)        Abstract:        Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal complexes via singlet-metal-carbene intermediates. However, previous transition-metal-catal...
04-25 2022
Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives...         yuanyuan ping,Xiao Li,qi pan,Wangqing Kong.Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives via Tunable Cyclization and 1,4-Acyl Transfer Triggered by Amide N-C Bond Cleavage.Angew. Chem. Int. Ed.(孔望清)        Abstract:        Ligand-directed divergent synthesis can transform common starting materials into distinct molecular scaffolds by simple tuning different ligands. ...
04-25 2022
Single-Junction Organic Solar Cells with 19.17% Efficiency En... ​        Rui Sun,Yao Wu,Xinrong Yang,Yuan Gao,Zeng Chen,Kai Li,Jiawei Qiao,Tao Wang,Jing Guo,Chao Liu,Xiaotao Hao,Haiming Zhu,Jie Min.Single-Junction Organic Solar Cells with 19.17% Efficiency Enabled by Introducing One Asymmetric Guest Acceptor.Advanced Materials(闵杰)        Abstract:        The ternary strategy has been widely identified as an effective approach to obtaining high-efficienc...