最新成果

当前位置: 首页 > 科学研究 > 最新成果
09-16 2022
Photocatalyzed Cascade Reactions of Cyclopropanols andα-Trif...         ​ Yunxiao Zhang,Yunhong Niu,Youyuan Guo,Jiaxin Wang,Yizhi Zhang,Shanshan Liu,Xiao Shen.Angew. Chem. Int. Ed(沈晓)Abstract:        A combination of photoredox catalysis and energy transfer catalysis/direct photo-excitation enables cascade reactions of cyclopropanols andα-CF3-olefins, in which two rings and three bonds are constructed in one reaction, affording fusedgem-difluorooxetan...
08-31 2022
From N-H nitration to controllable aromatic mononitration and...         Tao Yang,Xiaoqian Li,Shuang Deng,Xiaotian Qi,Hengjiang Cong,Hong-Gang Cheng,Liangwei Shi,Qianghui Zhou, and Lin Zhuang.JACS Au(庄林、周强辉、史良伟)Abstract:        Nitroaromatics are tremendously valuable organic compounds with a long history of being used as pharmaceuticals, agrochemicals, and explosives as well as vital intermediates to a wide variety of chemicals. Consequently, t...
08-31 2022
High-Performance Organic Photovoltaic Modules Using Eco-Frien...         Qiang Wu,Yue Yu,Xinxin Xia,Yuhan Gao,Tao Wang,Rui Sun,Jing Guo,Shanshan Wang,Guohua Xie,Xinhui Lu,Erjun Zhou,Jie Min.Joule(闵杰)        Abstract:        The development of the internet-of-thing (IoT) ecosystem has an urgent demand for convenient energy sources, such as indoororganic photovoltaics(IOPVs), to power IoT devices. However, the limited medium band-gap acceptors ...
08-31 2022
Synthesis of Cyclopentene Derivatives via Electrochemically I... ​        Zhipeng Guan,Shuxiang Zhu,Yayu Ye,Xiangwei Li,Yanlong Liu,Pengjie Wang,Prof. Heng Zhang,Dr. Zhiliang Huang,Prof. Aiwen Lei.Angew. Chem. Int. Ed.(雷爱文,张恒,黄志良)        Abstract:        Cyclopentenes are common cores in many natural products, and in bioactive and functional molecules. However, their synthesis remains challenging in terms of harsh conditions, poor selectivity, ...
08-31 2022
Electrophotochemical Ce-Catalyzed Ring-Opening Functionalizat...         Zhaoliang Yang,Dali Yang,Jianye Zhang,Chenyu Tan,Jiajun Li,Shengchun Wang,Heng Zhang,Zhiliang Huang*, and Aiwen Lei*. J. Am. Chem. Soc.(雷爱文,黄志良)        Abstract:        Selective cleavage and functionalization of C–C bonds in alcohols is gaining increasing interest in organic synthesis and biomass conversion. In particular, the development of redox-neutral catalytic methods w...
08-31 2022
Site-selective amination towards tertiary aliphatic allylamin...         Shengchun Wang,Yiming Gao,Zhao Liu,Demin Ren,He Sun,Linbin Niu,Dali Yang,Dongchao Zhang,Xing’an Liang,Renyi Shi,Xiaotian Qi&Aiwen Lei.Nature Catalysis(雷爱文,戚孝天)        Abstract:        Aliphatic allylamines are widely used for the synthesis of diverse building blocks for agrochemicals and pharmaceuticals; there is therefore considerable interest in developing versatile and dir...
07-08 2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ... ​       Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.(沈晓、蓝宇)       Abstract:       Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...