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08-31 2022
Site-selective amination towards tertiary aliphatic allylamin...         Shengchun Wang,Yiming Gao,Zhao Liu,Demin Ren,He Sun,Linbin Niu,Dali Yang,Dongchao Zhang,Xing’an Liang,Renyi Shi,Xiaotian Qi&Aiwen Lei.Nature Catalysis(雷爱文,戚孝天)        Abstract:        Aliphatic allylamines are widely used for the synthesis of diverse building blocks for agrochemicals and pharmaceuticals; there is therefore considerable interest in developing versatile and dir...
07-08 2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ... ​       Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.(沈晓、蓝宇)       Abstract:       Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...
05-17 2022
Dual-Resolving of Lipid Positional and Geometric Isomers of C...        Guifang Feng, Ming Gao, Liwei Wang, Jiayi Chen, Menglu Hou, Qiongqiong Wan, Yun Lin, Guoyong Xu, Xiaotian Qi & Suming Chen.Dual-resolving of positional and geometric isomers of C=C bonds via bifunctional photocycloaddition-photoisomerization reaction system.Nat. Commun.(陈素明)       Abstract:       The biological functions of lipids largely depend on their chemical structures. The po...
05-04 2022
Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Der... ​        Yizhi Zhang,Gang Zhou,Xingxing Gong,Zhuanzhuan Guo, Xiaotian Qi, Xiao Shen.Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Derived Carbenes to Alkenes.Angew. Chem. Int. Ed.(沈晓)        Abstract:        Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal complexes via singlet-metal-carbene intermediates. However, previous transition-metal-catal...
04-25 2022
Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives...         yuanyuan ping,Xiao Li,qi pan,Wangqing Kong.Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives via Tunable Cyclization and 1,4-Acyl Transfer Triggered by Amide N-C Bond Cleavage.Angew. Chem. Int. Ed.(孔望清)        Abstract:        Ligand-directed divergent synthesis can transform common starting materials into distinct molecular scaffolds by simple tuning different ligands. ...
04-25 2022
Single-Junction Organic Solar Cells with 19.17% Efficiency En... ​        Rui Sun,Yao Wu,Xinrong Yang,Yuan Gao,Zeng Chen,Kai Li,Jiawei Qiao,Tao Wang,Jing Guo,Chao Liu,Xiaotao Hao,Haiming Zhu,Jie Min.Single-Junction Organic Solar Cells with 19.17% Efficiency Enabled by Introducing One Asymmetric Guest Acceptor.Advanced Materials(闵杰)        Abstract:        The ternary strategy has been widely identified as an effective approach to obtaining high-efficienc...
03-01 2022
Tailoring polymer acceptors by electron linkers for achieving... Wu, Q., Wang, W., Wu, Y., Sun, R., Guo, J., Shi, MM., Min, J.Tailoring polymer acceptors by electron linkers for achieving efficient and stable all-polymer solar cells. National Science Review.(闵杰)AbstractThe trade-off between efficiency and stability is a bit vague, and it can be tricky to precisely control the bulk morphology to simultaneously improve device efficiency and stability. Herein...
12-01 2021
A New End Group on Nonfullerene Acceptors Endows Efficient Or... Pan, YW., Zheng, XJ., Guo, J., Chen, Z., Li, SX., He, CL.,…Min, J. (2021).A New End Group on Nonfullerene Acceptors Endows Efficient Organic Solar Cells with Low Energy Losses. Advanced Functional Materials.(闵杰)AbstractLarge energy loss is one of the main limiting factors for power conversion efficiencies (PCEs) of organic solar cells (OSCs). To this effect, the chemical modifications of the...
11-01 2021
Baseplate Temperature-Dependent Vertical Composition Gradient... Zheng, YN ., Sun, R., Zhang, M., Chen, ZH., Peng, ZX., Wu, Q., Yuan, XX… Min, J. (2021).Baseplate Temperature-Dependent Vertical Composition Gradient in Pseudo-Bilayer Films for Printing Non-Fullerene Organic Solar Cells.Advanced Energy Materials.(闵杰)AbstractNumerous previous reports on the sequential deposition (SD) technique have demonstrated that this approach can achieve a p-i-n active l...
11-01 2021
A Versatile Preparation of Mesoporous Single Layered Transiti... Zhang,X.,Weng,W., Gu,H., Hong,Z.,Xiao,W.,Wang,FR.,Li,W.,Gu,D. (2021).A Versatile Preparation of Mesoporous Single Layered Transition Metal Sulfide/Carbon Composites for Enhanced Sodium Storage.Advanced Materials.(顾栋)AbstractTransition-metal sulfides are promising electrochemical energy storage materials due to their abundant active sites, large interlayer space, and high theoretical capa...
10-01 2021
PEDOT:PSS-Free Polymer Non-Fullerene Polymer Solar Cells with... Sun, R.,Wang, T.,Wu,Y., Zhang, M.,…Min, J . (2021).PEDOT:PSS-Free Polymer Non-Fullerene Polymer Solar Cells with Efficiency up to 18.60% Employing a Binary-Solvent-Chlorinated ITO Anode. Advanced Functional Materials.(闵杰)AbstractDespite the tremendous development of different high-performing photovoltaic systems in non-fullerene polymer solar cells (PSCs), improving their performance is stil...
09-01 2021
General Synthesis of 2D Rare-Earth Oxides Single Crystals wit... ​Li, LY., Lu, FY., Xiong, WQ., Ding, Y.,Lu, YY., Xiao,Y.,…Fu, L.(2021). General Synthesis of 2D Rare-Earth Oxides Single Crystals with Tailorable Facet. National Science Review.(付磊)AbstractTwo-dimensional (2D) rare-earth oxides (REOs) are a large family of materials with various intriguing applications and precise facet control is essential for investigating new properties in the 2D limit. ...
09-01 2021
Recent advances in electrochemical oxidative cross-coupling w... Yuan, Y., Yang, J ., Lei, AW. (2021).Recent advances in electrochemical oxidative cross-coupling with hydrogen evolution involving radicals. Chemical Society Reviews.(雷爱文)AbstractOxidative cross-coupling has dev​eloped into a robust method for carbon-carbon (C-C), carbon-heteroatom (C-X), and heteroatom-heteroatom (X-Y) bond formation. Despite considerable advances in this field, the tradit...