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09-16 2022
Photocatalyzed Cascade Reactions of Cyclopropanols andα-Trif...         ​ Yunxiao Zhang,Yunhong Niu,Youyuan Guo,Jiaxin Wang,Yizhi Zhang,Shanshan Liu,Xiao Shen.Angew. Chem. Int. Ed(沈晓）Abstract:        A combination of photoredox catalysis and energy transfer catalysis/direct photo-excitation enables cascade reactions of cyclopropanols andα-CF3-olefins, in which two rings and three bonds are constructed in one reaction, affording fusedgem-difluorooxetan...
08-31 2022
From N-H nitration to controllable aromatic mononitration and...         Tao Yang,Xiaoqian Li,Shuang Deng,Xiaotian Qi,Hengjiang Cong,Hong-Gang Cheng,Liangwei Shi,Qianghui Zhou, and Lin Zhuang.JACS Au（庄林、周强辉、史良伟）Abstract：        Nitroaromatics are tremendously valuable organic compounds with a long history of being used as pharmaceuticals, agrochemicals, and explosives as well as vital intermediates to a wide variety of chemicals. Consequently, t...
08-31 2022
High-Performance Organic Photovoltaic Modules Using Eco-Frien...         Qiang Wu，Yue Yu，Xinxin Xia，Yuhan Gao，Tao Wang，Rui Sun，Jing Guo，Shanshan Wang，Guohua Xie，Xinhui Lu，Erjun Zhou，Jie Min.Joule（闵杰）        Abstract：        The development of the internet-of-thing (IoT) ecosystem has an urgent demand for convenient energy sources, such as indoororganic photovoltaics(IOPVs), to power IoT devices. However, the limited medium band-gap acceptors ...
08-31 2022
Synthesis of Cyclopentene Derivatives via Electrochemically I... ​        Zhipeng Guan,Shuxiang Zhu,Yayu Ye,Xiangwei Li,Yanlong Liu,Pengjie Wang,Prof. Heng Zhang,Dr. Zhiliang Huang,Prof. Aiwen Lei.Angew. Chem. Int. Ed.（雷爱文，张恒，黄志良）        Abstract：        Cyclopentenes are common cores in many natural products, and in bioactive and functional molecules. However, their synthesis remains challenging in terms of harsh conditions, poor selectivity, ...
08-31 2022
Electrophotochemical Ce-Catalyzed Ring-Opening Functionalizat...         Zhaoliang Yang,Dali Yang,Jianye Zhang,Chenyu Tan,Jiajun Li,Shengchun Wang,Heng Zhang,Zhiliang Huang*, and Aiwen Lei*. J. Am. Chem. Soc.（雷爱文，黄志良）        Abstract：        Selective cleavage and functionalization of C–C bonds in alcohols is gaining increasing interest in organic synthesis and biomass conversion. In particular, the development of redox-neutral catalytic methods w...
08-31 2022
Site-selective amination towards tertiary aliphatic allylamin...         Shengchun Wang,Yiming Gao,Zhao Liu,Demin Ren,He Sun,Linbin Niu,Dali Yang,Dongchao Zhang,Xing’an Liang,Renyi Shi,Xiaotian Qi&Aiwen Lei.Nature Catalysis（雷爱文，戚孝天）        Abstract：        Aliphatic allylamines are widely used for the synthesis of diverse building blocks for agrochemicals and pharmaceuticals; there is therefore considerable interest in developing versatile and dir...
07-08 2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ... ​       Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.（沈晓、蓝宇）       Abstract：       Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...
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