Bond Activations Assisted by Redox Active Ligand Scaffolds

作者:Khan, FF (Khan, Farheen Fatima)[ 1 ] ; Chowdhury, AD (Chowdhury, Abhishek Dutta)[ 2 ] ; Lahiri, GK (Lahiri, Goutam Kumar)[ 1 ]

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

卷: 2020 期: 13 页: 1138-1146

DOI: 10.1002/ejic.202000005

出版年: APR 7 2020

在线发表日期: FEB 2020

文献类型:Review

摘要

Redox active ligands are an integral part of many biological events and significant natural processes. Transformations assisted by such ligands gather the limelight owing to their excellent activity and selectivity towards the transformation of organic functionalities as well as activation of small molecules. The past few decades have seen an increasing demand of the field featuring its significance as the concept derived products find applications in chemical, pharmaceutical and agrochemical industries. Besides, the mechanistic insights allow for a grass root understanding of the underlining chemistry. The present article aims to highlight bond activations platformed on this concept by citing a few recent examples.

关键词

作者关键词:Redox chemistry; Bond activation; Radicals; Cleavage reactions; Ligand effects

KeyWords Plus:ALCOHOLS INCLUDING METHANOL; SMALL-MOLECULE ACTIVATION; ELECTRON-TRANSFER; DIOXYGEN ACTIVATION; METAL REACTIVITY; O-AMINOPHENOL; NONHEME IRON; C-H; COMPLEXES; CLEAVAGE

作者信息

通讯作者地址:

Indian Institute of Technology System (IIT System) Indian Institute of Technology (IIT) - Bombay Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India.

Wuhan University Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China.

通讯作者地址: Lahiri, GK (通讯作者)

Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India.

通讯作者地址: Chowdhury, AD (通讯作者)

Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China.

地址:

[ 1 ]‎ Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India

[ 2 ]‎ Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China

电子邮件地址:abhishek@whu.edu.cn; lahiri@chem.iitb.ac.in