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孔望清

作者:     点击:      时间:2018-10-08

                             

                             孔望清

教授,博士生导师

中组部青年千人计划入选者(第十三批)

邮箱:wqkong@whu.edu.cn

课题组主页:http://wqkong.whu.edu.cn


研究方向

1)金属有机化学:过渡金属不对称催化

2)自由基化学:发展新的策略实现自由基反应的立体选择性控制

3)开展具有生物活性天然产物和药物分子的高效合成研究

教育与研究经历

2017.04-至今 武汉大学高等研究院,教授

2014.10-2017.03   瑞士洛桑联邦理工大学 (EPFL),博士后,导师: Jieping Zhu

2011.09-2014.09   瑞士苏黎世大学 (UZH),博士后,导师: Cristina Nevado

2006.09-2011.06   浙江大学,博士,导师:麻生明教授(中国科学院院士)

荣誉与奖励

2017年入选青年千人计划

诺华制药博士后奖学金(2012

苏黎世大学博士后基金(2011

浙江省优秀毕业生(2011

宝钢优秀学生奖(2009

Publications

22. Kuai Wang, Zhengtian Ding, Zhijun Zhou, and Wangqing Kong*. Ni-Catalyzed Enantioselective Reductive Diarylation of Activated Alkenes by Domino Cyclization/Cross-Coupling. J. Am. Chem. Soc., 2018, 140, 12364-12368.

21. Yuanyuan Ping, Yuxiu Li, Jieping Zhu*, Wangqing Kong*. Construction of Quaternary Stereocenters by PalladiumCatalyzed CarbopalladationInitiated Cascade Reactions. Angew. Chem. Int. Ed. 2018, DOI: 10.1002/anie.201806088.

20. Yuxiu Li, Kuai Wang, Yuanyuan Ping, Yifan Wang, and Wangqing Kong*. Nickel-Catalyzed Domino Heck Cyclization/Suzuki Coupling for the Synthesis of 3,3-Disubstituted Oxindoles. Org. Lett. 2018, 20, 921−924 (Highlighted by Synfacts, 2018, 14(4), 410)

19. Kuai Wang, Wangqing Kong*. Recent Advances in Transition Metal Catalyzed Asymmetric Radical Reactions. Chin. J. Chem. 2018, 36, 247-256. (Cover Story)

Before independent work:

18. Wangqing Kong, Qian Wang, Jieping Zhu*. Water as hydride source in palladium-catalyzed enantioselective reductive Heck reaction. Angew. Chem. Int. Ed. 2017, 56, 3987-3991. (Chosen by the Editors as a “Hot Paper”) (Highlighted by Synfacts, 2017, 13(5), 495) (Highly Cited Paper)

17. Wangqing Kong, Qian Wang, Jieping Zhu*. Switchable synthesis of diversely functionalized oxindoles enabled by migratory insertion of isocyanide to a transient σ-alkylpalladium(II) complex. Angew. Chem. Int. Ed. 2016, 55, 9714-9718.

16. Wangqing Kong, Qian Wang, Jieping Zhu*. Palladium-catalyzed enantioselective domino heck/intermolecular C-H bond functionalization: Development and application to the synthesis of (+)-esermethole. J. Am. Chem. Soc. 2015, 137, 16028-16031. (Highlighted by Synfacts, 2016, 12(3), 274.)

15. Wangqing Kong, Noelia Fuentes, Andres García-Domínguez, Estíbaliz Merino, Cristina Nevado*. Stereoselective synthesis of highly functionalized indanes and dibenzocycloheptadienes via complex radical cascades. Angew. Chem. Int. Ed. 2015, 54, 2487-2491.

14. Noelia Fuentes, Wangqing Kong, Luis Fernández-Sánchez, Estíbaliz Merino, Cristina Nevado*. Cyclization cascades via N-amidyl radicals toward highly functionalized heterocyclic scaffolds. J. Am. Chem. Soc. 2015, 137, 964-973. (Highly Cited Paper)

13. Wangqing Kong, Estíbaliz Merino, Cristina Nevado*. Arylphosphonylation and arylazidation of activated alkenes. Angew. Chem. Int. Ed. 2014, 53, 5078-5082. (Chosen by the Editors as a “Hot Paper”) (Highly Cited Paper)

12. Wangqing Kong, Estíbaliz Merino, Cristina Nevado*. Divergent reaction mechanism in the aminofluorination of alkenes. CHIMIA International Journal for Chemistry, 2014, 68, 430-435.

11. Wangqing Kong, Maria Casimiro, Noelia Fuentes, Estíbaliz Merino, Cristina Nevado*. Metal-free aryltrifluoromethylation of activated alkenes. Angew. Chem. Int. Ed. 2013, 52, 13086-13090. (Highly Cited Paper)

10. Wangqing Kong, Maria Casimiro, Estibaliz Merino, Cristina Nevado*. Copper-catalyzed 1-pot trifluoromethylation/arylmigration/desulfonylation and Csp2-N bond formation of conjugated tosyl amides. J. Am. Chem. Soc. 2013, 135, 14480-14483. (Highly Cited Paper)

9. Wangqing Kong, Pascal Feige, Teresa de Haro, Cristina Nevado*. Regio- and enantioselective aminofluorination of alkenes. Angew. Chem. Int. Ed. 2013, 52, 2469-2473. (Highlighted by Synfacts 2013, 9 (4), 371 and Organic Chemistry Portal 2014, March 17.) (Highly Cited Paper)

8. Wangqing Kong, Youai Qiu, Xue Zhang, Chunling Fu, Shengming Ma*. Exclusive 1,2-aryl shift in Platinum(II) chloride-catalyzed cyclization of 1-(indol-2-yl)-2,3-allenols. Adv. Synth. Catal. 2012, 354, 2339-2347.

7. Wangqing Kong, Chunling Fu, Shengming Ma*. Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism. Org. Biomol. Chem. 2012, 10, 2164-2173.

6. Wangqing Kong, Chunling Fu, Shengming Ma*. General Au-catalyzed benzannulation towards naturally occurring carbazole alkaloids from methoxypropadiene. Chem. Eur. J. 2011, 17, 13134-13137.

5. Wangqing Kong, Binjie Guo, Chunling Fu, Shengming Ma*. An efficient approach to 2-bromoalken-3-ols by regioselective bromohydroxylation reaction of simple allenes with NBS. Eur. J. Org. Chem. 2011, 2278-2285.

4. Wangqing Kong, Chunling Fu, Shengming Ma*. An efficient synthesis of polysubstituted naphthalene derivatives by gold-catalyzed cyclization of 1-arylalka-2,3-dienyl acetates. Eur. J. Org. Chem. 2010, 6545-6555.(Cover Story)

3. Wangqing Kong, Jie Cui, Yihua Yu, Guofei Chen, Chunling Fu, Shengming Ma*. PtCl4-catalyzed cyclization reaction of β-allenols in the presence of indole. Org. Lett. 2009, 11, 1213-1216.

2. Wangqing Kong, Chunling Fu, Shengming Ma*. An efficient synthesis of carbazoles from PtCl2-catalyzed cyclization of 1-(indol-2-yl)-2,3-allenols. Chem. Commun. 2009, 4572–4574.

1. Wangqing Kong, Chunling Fu, Shengming Ma*. Indium and zinc-mediated Barbier-type addition reaction of 2,3-allenals with allyl bromide: an efficient synthesis of 1,5,6-alkatrien-4-ols. Org. Biomol. Chem. 2008, 6, 4587–4592.

专利

1.一种合成咔唑类化合物的方法,专利号:ZL 200910099482.X

2.一种合成咔唑类生物碱 Siamenol 的方法,专利号:ZL 201110283659.9

3.一种合成天然咔唑类生物碱的制备方法,专利号:ZL 201110283147.2

4.一种合成咔唑类化合物的方法,专利号:ZL 201210516430.X

 

课题组招贤纳才

博士后

  薪酬待遇:工资及福利待遇根据武汉大学相关规定从优考虑(五险一金,解决户口和子女入学等问题);并根据工作业绩额外发放津贴(预计年薪25-30万元,具体薪资待遇面议);可作为负责人申请博后基金、国家青年基金、和湖北省相关基金。博士后期间特别优秀者可协助申请武汉大学正式教师(非独立成组)。

职位要求:

1)有机化学博士,有写作和发表英文科技论文经历。

2)有团队精神,工作踏实,有责任感,易沟通。

3)有金属有机化学(特别是过渡金属不对称催化)或自由基化学研究经历者优先考虑。

请发送个人简历、主要研究成果等相关资料到:wqkong@whu.edu.cn

研究助理2-3

薪酬待遇:将提供具有竞争力的薪酬待遇,并根据工作业绩额外发放津贴,可优先报考硕士或者博士研究生。

职位要求:

1)本科或硕士学位,化学相关专业,熟悉常规有机化学实验技术和操作。

2)工作踏实,有责任感,具有良好的沟通能力和合作精神。

3)英语良好,能独立阅读英文文献。

请发送个人简历及其他能证明本人能力的相关资料到:wqkong@whu.edu.cn

研究生

  欢迎全国的优秀学子报考本小组的博士或硕士研究生。要求专业基础扎实,工作踏实,有团队精神,具有良好的沟通能力。我们将提供具有竞争力的待遇,并根据工作业绩额外发放津贴。有意者请直接邮件联系wqkong@whu.edu.cn

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