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Recent Advances in Radical C-H Activation/Radical Cross-Coupling

作者:     点击:      时间:2018-06-01

Yi, H (Yi, Hong)[ 1 ] ; Zhang, GT (Zhang, Guoting)[ 1 ] ; Wang, HM (Wang, Huamin)[ 1 ] ; Huang, ZY (Huang, Zhiyuan)[ 1 ] ; Wang, J (Wang, Jue)[ 1 ] ; Singh, AK (Singh, Atul K.)[ 1 ] ; Lei, AW (Lei, Aiwen)[ 1,2 ]


CHEMICAL REVIEWS

卷: 117

期: 13

页: 9016-9085

DOI: 10.1021/acs.chemrev.6b00620

出版年: JUL 12 2017

文献类型:Review


摘要

Research and industrial interest in radical C-H activation/radical cross coupling chemistry has continuously grown over the past few decades. These reactions offer fascinating and unconventional approaches toward connecting molecular fragments with high atom- and step-economy that are often complementary to traditional methods. Success in this area of research was made possible through the development of photocatalysis and first-row transition metal catalysis along with the use of peroxides as radical initiators. This Review provides a brief and concise overview of the current status and latest methodologies using radicals or radical cations as key intermediates produced via radical C-H activation. This Review includes radical addition, radical cascade cyclization, radical/radical cross-coupling, coupling of radicals with M-R groups, and coupling of radical cations with nucleophiles (Nu).

作者信息

通讯作者地址: Lei, AW (通讯作者)

显示更多 Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China.
通讯作者地址: Lei, AW (通讯作者)
显示更多 Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China.

地址:

[ 1 ] Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[ 2 ] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

电子邮件地址:aiwenlei@whu.edu.cn


原文PDF链接:

https://pubs.acs.org/doi/10.1021/acs.chemrev.6b00620